Those who’ve had the privilege of seeing Chance The Rapper live know the adventurous Chicago MC is not only a spazz on the mic — he also can barely contain his physical being, bouncing all over the stage with contagious burning emotion. Now a national TV audience knows that too: Chance made his television debut last night on The Arsenio Hall Show performing the Acid Rap highlight “Chain Smoker.” He also talked to Arsenio for about five minutes, calling for peace in gang-riddled Chicago and explaining his idea for a rappers’ union. Watch it all below.

Acid Rap is out now as a free download, and it made our list of 2013’s best rap albums and best albums overall.